Anyone traveling on a highway has probably seen diamond shaped placards on trucks. These are multicolored and generally have numbers within some of the colors. If you wondered the meaning of these numbers here is the answer.
The diamond displayed on trucks refers to the National Fire Protection Association (NFPA) hazard code. This code system is detailed in NFPA 704 rating system. The diamond shaped placard has four smaller diamonds within the larger one. The top diamond is colored red and refers to the flammability of the material being carried by the truck. The left side of the diamond is blue. The blue diamond is the health safety of the material being transported. The right diamond is yellow and speaks to the reactivity of the material being transported. The bottom diamond is white and is used for special warnings. Consider each category.

The blue health codes are numbered from 0-4
4 – Very short exposure to material can cause death or major residual injury even with prompt medical treatment.
3 – Short exposure to material can cause serious temporary or residual injury even with prompt medical treatment.
2 – Intense or continued exposure to material can cause temporary incapacitation or residual injury unless prompt medical treatment is administered.
1 – Exposure to material will cause irritation but only minor residual injury even with no treatment.
0 – Exposure to material under fire conditions will offer no hazard beyond that of ordinary combustible material.
The red flammability codes are also numbered from 0-4
4 – Material will rapidly or completely vaporize at atmospheric pressure and normal temperature, or will burn readily when dispersed in air.
3 – A liquid or solid (class I-B and C) that can be ignited under almost all ambient temperature conditions.
2 – Solid or liquid (class II and III-A) that can be ignited under almost all ambient temperature conditions.
1 – Material that must be preheated before ignition can occur.
0 – Material that will not burn.
The yellow, reactivity diamonds also contains numbers from 0-4.
4 – Material that is readily capable of detonation or explosive decomposition or reaction at normal temperatures and pressures.
3 – Material that is readily capable of detonation or explosive reaction but requires a strong initiating source or which must be heated under confinement before initiation or may react explosively with water.
2 – Material that is normally unstable and readily undergoes violent chemical change but does not detonate. Also, may react violently with water or may form potentially explosive mixtures with water.
1 – Material is normally stable but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently.
0 – Material is normally stable even under fire exposure conditions and is not reactive with water.
The white diamond at the bottom contains special warnings. The letters “OX” designates oxidizing material. A letter “W” with a strike through means the material is hazardous when in contact with moisture or water. You may see other designations in the white diamond that are not part of the NFPA standard. These frequently include BIO for biological hazard, COR for corrosive, CYL or CRYO for cryogenic, SA for asphyxiant gas.
Generally a zero indicates minimal hazard and a four indicates severe hazard. The same placard system is also used at locations where these materials are stored. The system allows first responders to access how to best deal with emergency situations involving these materials. Wall charts and wallet cards are published to serve as a guide for anyone that must deal with these materials.